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What is electrophilic substitution? . . .
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Some background on benzene (including links to more detailed discussions) and a general mechanism which covers several of benzene's reactions.
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The nitration of benzene . . .
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The mechanism for the formation of nitrobenzene from benzene.
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The Friedel-Crafts acylation of benzene . . .
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The mechanism for the substitution of an acyl group such as CH3CO into benzene.
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The Friedel-Crafts alkylation of benzene . . .
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The mechanism for the substitution of an alkyl group such as CH3 into benzene.
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An industrial alkylation of benzene . . .
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The mechanism for the substitution of an alkyl group such as CH3CH2 into benzene, by a reaction involving an alkene such as ethene.
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The halogenation of benzene . . .
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The mechanism for the substitution of atoms like chlorine and bromine into benzene rings.
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The sulphonation of benzene . . .
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The mechanism for reaction between benzene and concentrated sulphuric acid to produce benzenesulphonic acid
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Some substitution reactions of methylbenzene . . .
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Illustrates how to cope with the problem of substituting things into rings which already have something else attached.