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FREE RADICAL MECHANISMS MENU
Free radical substitution
A brief explanation of the terms free radical and substitution. Free radical substitution of hydrogen atoms in methane by chlorine atoms. Includes multiple substitution if you need it. Free radical substitution of hydrogen atoms in methane by bromine atoms. Includes multiple substitution if you need it. Free radical substitution of hydrogen atoms in the methyl group in methylbenzene by chlorine atoms in the presence of UV light (sunlight). Includes multiple substitution if you need it.
Free radical addition
The mechanism for the polymerisation of ethene under free radical conditions. The mechanism for the addition of hydrogen bromide to alkenes under free radical conditions. This is often known as the "peroxide effect".
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